Friday, July 8, 2011

The Devil and a Dingbat: Sid Harth

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Of Rattle-Tattle. and India’s ENR Battle: Sid Harth

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The nuclear limit

  • July 8, 2011
  • By Arun Kumar Singh
  • DC
 There has been some heated discussion in the media about the latest decision of the Nuclear Suppliers Group (NSG) to ban the supply of Enrichment and Reprocessing (ENR) equipment to India, despite the earlier Indo-US nuclear deal and the 2008 “clean waiver” accorded to India by the International Atomic Energy Agency (IAEA).
Fortunately, the three main suppliers (the US, Russia and France) have issued statements declaring their intent to honour all bilateral agreements. Let’s hope and pray that they honour their words with deeds and that India’s leadership is not led up the garden path yet again.
While India does have some limited indigenous ENR capability, it requires modern ENR facilities to ensure optimum use of the imported uranium. Why is ENR necessary? The answer to this lies in the peculiar process which low-enriched uranium-235 (U-235), (though initially in a critical mass in the reactor fuel core) undergoes during fission in a power reactor, wherein byproducts (called “poisons”) like iodine etc. are formed. These absorb neutrons, thereby making the reactor fuel core “sub critical” and incapable of generating power.
The problem is overcome by initially adding “excess reactivity” with more enriched U-235, to ensure a few more years of operation before reactor fuel change. Reactor fuel change is a complex process that requires stringent safety measures, including storage facility for used fuel (in Fukushima two reactors with used fuel stored were also affected by the earthquake and tsunami), before transporting it for reprocessing where plutonium-239 (Pu-239) is removed for use in either fast breeder reactors or for making weapons — this latter use is the worry of IAEA-NSG, as they fear that Indian scientists may reverse-engineer the latest ENR technology to upgrade existing indigenous ENR equipment to enhance their capacity or to build new “indigenous” ENR plants, both of which would not be under IAEA safeguards.
Also, some of the used U-235 can be isolated from the “poisons” and enriched for possible reuse, and this would need IAEA monitoring.
However, one cannot deny that India needs some nuclear power, despite Germany’s latest decision, post-Fukushima nuclear disaster, to have zero nuclear power by 2022. But we need to proceed with great caution and the realisation that nuclear power in India can never contribute more than 10 per cent to the national power grid, for reasons of safety, availability of highly specialised operators and economics. Nuclear safety lessons from the American Three Mile Island, the Soviet Chernobyl and the Japanese Fukushima accidents must be kept in mind, as also our inept handling of the 1984 Bhopal gas tragedy.
There is no doubt that the March 11 nuclear disaster in earthquake-prone Japan was due to a combination of various factors, including faulty location of the reactors and the standby diesel generators for emergency reactor cooling, the flawed decision to delay use of sea water cooling.
Japan’s decision to decommission four of the six Fukushima reactors will not mean the end of nuclear emergency since these reactors, after being entombed in sand, lead and concrete, will require monitoring for a very long time because while some reactor “fission byproducts” like iodine have very short half-lives and decay quickly, others have very long half-lives, for example strontium-90 (29 years) and cesium-137 (30 years). The plutonium found in the soil in Fukushima has a half-life of 24,400 years.
I have always been a strong supporter of “limited” nuclear power (which would meet about 10 per cent of our energy needs), provided the nuclear plants are safely located (away from population centres and seismic zones), built as per the latest, stringent IAEA safety standards, are operated by skilled personnel and audited regularly for safety. In addition, I have always supported a strict Nuclear Liabilities Bill (NLB), an efficient National Disaster Management System (NDMS) with dedicated Nuclear Emergency Response Teams (NERT) and a three-minute automated Tsunami Warning System (TWS), unlike the present 30-minute Indian warning system which is reported to be non-operational due to pilferage of the buoys at sea by fishermen.
Despite the obvious lessons of the latest nuclear disaster in Japan, and the limitations of India’s NLB, NDMS, NERT and TWS, I am amazed that India’s Department of Atomic Energy (DAE) has reportedly projected a requirement of 6,55,000 MWe of nuclear power by 2050. This would involve setting up about 655 additional imported reactors of 1000 MWe each, in “nuclear parks” of about six reactors per “park” each.
Given mainland India’s 6,000 km coastline, India could have 109 “nuclear parks”, about 55 km apart, dotting its coastline, which would be a recipe for major disasters, given worries of tsunamis, earthquakes, or a terrorist strike. Given India’s total projected power need of 1350,000 MWe by 2050, the DAE-reported proposal to meet 50 per cent of the country’s energy needs by nuclear power, if indeed true, is sheer madness. It makes no sense, it is not safe and it is not affordable.
It’s time for sanity to return. A transparent public audit needs to be done of India’s nuclear safety standards, availability of skilled manpower, suitable non-seismic zone cum unpopulated site locations, as well as NDMS, NERT and TWS. If these audits are done properly, India may discover that it will be able to afford and set up about 40 reactors (of which half would be indigenous) by 2050.
The balance power requirements would require greater exploitation of renewable energy sources like solar, hydro and wind power, along with the traditional “heavyweights” like coal, which Australia is willing to export, unlike U-235. New technologies are available, though at present expensive, to deliver “clean energy” from coal.
The author, a vice-admiral, retired as Flag Officer Commanding-in-Chief of the Eastern Naval Command, Visakhapatnam

My dear
Arun Kumar Singh,
For writing an article on the most controversial Nuclear Reprocessing Regimen in one single stroke, I give you, a Veer Chakra, oops, Param Veer Chakram. Oops, Award. A ward of some Indian asylum for the mad scientists you must be. However, the battle plans you suggested, and I quote:
“Fortunately, the three main suppliers (the US, Russia and France) have issued statements declaring their intent to honour all bilateral agreements. Let’s hope and pray that they honour their words with deeds and that India’s leadership is not led up the garden path yet again.
You are kidding, are you? Any statement made by a foreign country would rethink their earlier policies when a push comes to shove. Moreover, the big daddy, oops, Uncle Sam can be patient so much. If one just observes USA’s previous behavior, they are going to put pressure upon these three nuclear nations, one way or other.
Let us say, they may or they may not. Depends upon which party is going to win the next general, oops, presidential election. If barack Husein Obama wins it and he wants India to be behaving like a good little, third world, third rate country and buys from USA more military, industrial and consumer products with or without mental reservation and not encouraging other European countries like Germany, France, Great Britain to have secret dealings not approved by the NSG top dogs, things would sour for India’s superpower dream, oops, a day dream.
Have a nice day.
…and I am Sid harth@mysistereileen.com
Copyright © 2011 Deccan Chronicle. All rights reserved. For reprint rights: Deccan Chronicle Service
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Use of Secondary Ion Mass Spectrometry in Nuclear Forensic Analysis for the Characterization of Plutonium and Highly Enriched Uranium Particles

Maria Betti,* Gabriele Tamborini, and Lothar Koch
European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe, Germany
Anal. Chem., 1999, 71 (14), pp 2616–2622
DOI: 10.1021/ac981184r
Publication Date (Web): June 10, 1999
Copyright © 1999 American Chemical Society

Abstract

The application of secondary ion mass spectrometry (SIMS) analysis is described for the characterization of plutonium and highly enriched uranium (HEU) particles with a diameter to 10 μm. Applying a method previously described, particles of HEU could be detected in a scrap material, together with natural uranium. The isotopic composition of the particles was measured with a typical accuracy and precision of 0.5%. The spectrum of the trace elements in the uranium particles was also recorded. From the results it was possible to deduce that the uranium oxide, as UO2, was produced via a pyrochemical process. In a sample consisting of a mixture of three different species of particles, two of these were identified as plutonium particles. They were characterized according to their isotopic ratio 239/240 as well as to their dimension and shape. The results obtained by SIMS for the isotopic ratio were compared with those obtained analyzing the particles by Thermal Ionization Mass Spectrometry (TIMS). The shape and dimensions were confirmed by the analysis with Scanning Electron Microscopy (SEM). In both the cases the results obtained by SIMS were in good agreement with those from TIMS and SEM.

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Cover Image: May 2008 Scientific American Magazine See Inside

Nuclear Fuel Recycling: More Trouble Than It’s Worth

Plans are afoot to reuse spent reactor fuel in the U.S. But the advantages of the scheme pale in comparison with its dangers
By Frank N. von Hippel  | April 28, 2008 | 28

LA HAGUE, on France’s Normandy coast, hosts a large complex that reprocesses spent fuel from nuclear power plants, extracting its plutonium for fabrication into new fuel. The U.S. Depart�ment of Energy has recently proposed building a similar facility. Image: Martin Bond: Photo Researchers, Inc.

In Brief

  • Spent nuclear fuel contains plutonium, which can be extracted and used in new fuel.
  • To reduce the amount of long-lived radioactive waste, the U.S. Department of Energy has proposed reprocessing spent fuel in this way and then “burning” the plutonium in special reactors.
  • But reprocessing is very expensive. Also, spent fuel emits lethal radiation, whereas separated plutonium can be handled easily. So reprocessing invites the possibility that terrorists might steal plutonium and construct an atom bomb.
  • The author argues against reprocessing and for storing the waste in casks until an underground repository is ready.
Although a dozen years have elapsed since any new nuclear power reactor has come online in the U.S., there are now stirrings of a nuclear renaissance. The incentives are certainly in place: the costs of natural gas and oil have skyrocketed; the public increasingly objects to the greenhouse gas emissions from burning fossil fuels; and the federal government has offered up to $8 billion in subsidies and insurance against delays in licensing (with new laws to streamline the process) and $18.5 billion in loan guarantees. What more could the moribund nuclear power industry possibly want?
Just one thing: a place to ship its used reactor fuel. Indeed, the lack of a disposal site remains a dark cloud hanging over the entire enterprise. The projected opening of a federal waste storage repository in Yucca Mountain in Nevada (now anticipated for 2017 at the earliest) has already slipped by two decades, and the cooling pools holding spent fuel at the nation’s nuclear power plants are running out of space.
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28 Comments

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  1. 1. Redxxx 03:59 PM 4/28/08
    Grasping my reasons for rejecting nuclear fuel reprocessing requires nothing more than a rudimentary understanding of the nuclear fuel cycle and a dollop of common sense.Reply | Report Abuse | Link to this


  2. 2. doc_halidai 06:05 PM 4/28/08
    If the waste products are still producing heat, why not set up some kind of engine (like a Stirling engine) to generate power from this heat? Who cares if the efficiency is low, if nothing else, it would help to pay for the waste storage.Reply | Report Abuse | Link to this


  3. 3. CraigC762 11:12 PM 4/28/08
    Will the eco-hippies stop at nothing to torpedo any real solutions to the energy dependence problem?”More trouble than it’s worth?”Is plunging the entire country into the dark whenever the sun stops shining (i.e. night time) or the wind stops blowing worth the “clear conscience” that leftists tell us solar / wind technology will bring? Reply | Report Abuse | Link to this


  4. 4. snapperman2 02:11 AM 4/29/08
    According to this article it seems that nuclear waste generates significant amounts of energy for very long periods of time. It states that 10 tons of waste generates 10 kilowatts of heat. Rather than burying this waste at Yucca mountain, why not use this waste to generate more energy. If you collected all of the nuclear waste that has been produced in the U.S. and put it in a pool of water at such a density that the heat generated by the waste caused the water to boil, you could use the steam to drive a turbine and generate electricity. You could use a closed system so that the steam was condensed back into water and went back into the pool, thus avoiding the danger of radioactive steam leaking out into the environment. That way you could have a source of power for thousands of years until the nuclear waste degraded, and you wouldn�”t need to worry about disposing of the waste because it was doing something useful.Reply | Report Abuse | Link to this


  5. 5. John_Toradze 02:27 AM 4/29/08
    > You could use a closed system so that the steam was condensed back into water and went back into the pool, thus avoiding the danger of radioactive steam leaking out into the environment. …Ahem. You have just designed a nuclear reactor that uses low quality fuel. :-)You sitll have the problems of transmutation of elements in the reactor machinery causing failures due to neutron bombardments. And piping and such won’t last thousands of years. Aside from that, I think the article is ridiculous. Reprocessing works, and the reason France and Japan do it is that it is a cost effective solution. Enriching uranium is expensive and hazardous also. And all the uranium waste in the world pales by comparison with the radioactives spewed from coal ash every year. I posted that elsewhere, showing the calculation that 3 – 5 times (conservatively) the amount of uranium mined every year globally is put into the atmosphere as coal ash each year. – Edited by John_Toradze at 04/28/2008 7:28 PM Reply | Report Abuse | Link to this


  6. 6. TheArchitect 03:09 AM 4/29/08
    This could all be avoided by the use of a method known as Remix & Return. With this method the waste is blended with uranium ore mining waste until it is down to its original radioactivity level. In this form the waste could be buried without restriction and avoid the whole need for the Yucca facility.Reply | Report Abuse | Link to this


  7. 7. Nathan2go 05:48 AM 4/29/08
    Three major problems with the article: 1) it describes the 1960′s vintage Purex recycling rather than the more modern IFR recycling. Unlike purex, IFR only partially separates the plutonium, so it is not bomb-ready, and it’s still highly radioactive. 2) Unlike once-thru reactor cycles, breeder cycles have an almost in-exhaustible energy source. They are 100 times more fuel efficient. This makes them appealing in the long term. 3) Any discussion of the cost of reprocessing should include the apparent low-price leader: the 2 fluid molten salt breeder reactor running on thorium. This is the forgotten ugly stepchild of the reactor industry, but it has very simple reprocessing.Reply | Report Abuse | Link to this


  8. 8. Hugh Jones 02:23 PM 4/29/08
    All this over exhuming some ancient technology. Frankenstein in a tuxedo is still Frankenstein! R.I.P.Reply | Report Abuse | Link to this


  9. 9. ParetoJ 05:26 PM 4/29/08
    CANDU reactors can use other reactors’ spent fuel directly, ‘direct use of spent PWR fuel in CANDU’ (DUPIC). A lot of ‘waste’ material can be utilized, you just need a heavy water reactor like Canada has.Reply | Report Abuse | Link to this


  10. 10. Barry U. Headinsand 05:54 PM 4/29/08
    I felt that the article was pretty weak. The main points it made – that waste reprocessing/recycling is a bad idea because of nuclear terrorism & the great expense – are political policy issues, not scientific or manufacturing obstacles, & can both be resolved by an appropriate commitment of security & funding. Also, the article seems to have totally disregarded the statements from the Sci Am December ’05 article which states that reprocessing would result in a 95% reduction in half-life of nuclear waste. I, too, have concerns & apprehensions about nuclear power, but a sensible discussion of it’s appropriate place in our society is not advanced by political propaganda masquerading as scientific research.Reply | Report Abuse | Link to this

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Belfer Center Home > Publications > Academic Papers & Reports > Reports > The Economics of Reprocessing vs. Direct Disposal of Spent Nuclear Fuel

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<em>The Economics of Reprocessing vs. Direct Disposal of Spent Nuclear Fuel</em>” border=”0″ /></div>
<h1><strong><em>The Economics of Reprocessing vs. Direct Disposal of Spent Nuclear Fuel</em></strong></h1>
<p>Report, <a href=Project on Managing the Atom, Belfer Center for Science and International Affairs, Harvard Kennedy School December 2003
Authors: Bob van der Zwaan, Former Research Associate, Energy Technology Innovation Research Group/Project on Managing the Atom Project/Science, Technology, and Public Policy Program, 2001-2005, John P. Holdren, Former Director and Faculty Chair, Science, Technology and Public Policy Program (on leave), Steve Fetter, Former Associate, Science, Technology, and Public Policy Program, Matthew Bunn, Associate Professor of Public Policy; Co-Principal Investigator, Project on Managing the Atom; Co-Principal Investigator, Energy Research, Development, Demonstration, and Deployment (ERD3) Policy Project
Belfer Center Programs or Projects: International Security; Science, Technology, and Public Policy; Managing the Atom

Executive Summary
For decades, there has been an intense debate over the best approach to managing spent fuel from nuclear power reactors, whether it is better to dispose of it directly in geologic repositories, or reprocess it to recover and recycle the plutonium and uranium, disposing only of the wastes from reprocessing and recycling. The relative costs of reprocessing vs. not reprocessing are one important element of these debates. Economics is not the only or even the principal factor affecting decisions concerning reprocessing today. But economics is not unimportant, particularly in a nuclear industry facing an increasingly competitive environment. At a minimum, if reprocessing is being done to achieve objectives other than economic ones, it is worthwhile to know how much one is paying to achieve those other objectives.
While some analysts have argued in recent years that the costs of reprocessing and direct disposal are similar, and that reprocessing will soon be the more cost-effective approach as uranium prices increase, the data and analyses presented in this report demonstrate that the margin between the cost of reprocessing and recycling and that of direct disposal is wide, and is likely to persist for many decades to come. In particular:
• At a reprocessing price of $1000 per kilogram of heavy metal (kgHM), and with our other central estimates for the key fuel cycle parameters, reprocessing and recycling plutonium in existing light-water reactors (LWRs) will be more expensive than direct disposal of spent fuel until the uranium price reaches over $360 per kilogram of uranium (kgU).a price that is not likely to be seen for many decades, if then.
• At a uranium price of $40/kgU (comparable to current prices), reprocessing and recycling at a reprocessing price of $1000/kgHM would increase the cost of nuclear electricity by 1.3 mills/kWh. Since the total back-end cost for the direct disposal is in the range of 1.5 mills/kgWh, this represents more than an 80% increase in the costs attributable to spent fuel management (after taking account of appropriate credits or charges for recovered plutonium and uranium from reprocessing).
• These figures for breakeven uranium price and contribution to the cost of electricity are conservative, because, to ensure that our conclusions were robust, we have assumed:
-  A central estimate of reprocessing cost, $1000/kgHM, which is substantially below the cost that would pertain in privately financed facilities with identical costs and capacities to the large commercial facilities now in operation.
-  A central estimate of plutonium fuel fabrication cost, $1500/kgHM, which is significantly below the price actually offered to most utilities in the 1980s and 1990s.
-  Zero charges for storage of separated plutonium or removal of americium.
-  Zero additional security, licensing, or shut-down expenses for the use of plutonium fuels in existing reactors.
-  A full charge for 40 years of interim storage in dry casks for all fuel going to direct disposal, and no interim storage charge for fuel going to reprocessing.
Even though most new reactors are built with storage capacity for their lifetime fuel generation, so few additional costs for interim storage need be incurred.
-  Geological disposal of spent MOX fuel at the same cost as disposal of spent LEU fuel.
• Reprocessing and recycling plutonium in fast-neutron reactors (FRs) with an additional capital cost, compared to new LWRs, of $200/kWe installed will not be economically competitive with a once-through cycle in LWRs until the price of uranium reaches some $340/kgU, given our central estimates of the other parameters. Even if the capital cost of new FRs could be reduced to equal that of new LWRs, recycling in FRs would not be economic until the uranium price reached some $140/kgU.
• At a uranium price of $40/kgU, electricity from a plutonium-recycling FR with an additional capital cost of $200/kWe, and with our central estimates of the other parameters, would cost more than 7 mills/kWh more than electricity from a oncethrough LWR. Even if the additional capital cost could be eliminated, the extra electricity cost would be over 2 mills/kWh.
• As with reprocessing and recycling in LWRs, these figures on breakeven uranium price and extra electricity cost for FRs are conservative, as we have assumed:
-  Zero cost for providing start-up plutonium for the FRs.
-  Zero additional cost for reprocessing higher-plutonium-content FR fuel.
-  Zero additional cost for manufacturing higher-plutonium-content FR fuel.
-  Zero additional operations and maintenance costs for FRs, compared to LWRs.
• Costs for the far more complex chemical separations processes and more difficult fuel fabrication processes needed for more complete separation and transmutation of nuclear wastes would be substantially higher than those estimated here for traditional reprocessing. Therefore the extra electricity cost, were these approaches to be pursued, would be even higher. Arguments for separations and transmutation to limit the need for additional repositories rest on a number of critical assumptions that may or may not be borne out in practice.
• World resources of uranium likely to be economically recoverable in future decades at prices far below the breakeven price amount to tens of millions of tons, probably enough to fuel a rapidly-growing nuclear enterprise using a once-through fuel cycle for a century or more.
In this report, we have focused only on the economic issues, and have not examined other issues in the broader debate over reprocessing. Nevertheless, given (a) the costs outlined above; (b) the significant proliferation concerns that have been raised (particularly with respect to those reprocessing approaches that result in fully separated plutonium suitable for use in nuclear explosives); and (c) the availability of safe, proven, low-cost dry cask storage technology that will allow spent fuel to be stored for many decades, the burden of proof clearly rests on those in favor of investing in reprocessing in the near term.

For more information about this publication please contact the MTA Project Coordinator at 617-495-4219.
For Academic Citation:
Bunn, Matthew, Steve Fetter, John Holdren, and Bob van der Zwaan. The Economics of Reprocessing vs. Direct Disposal of Spent Nuclear Fuel. Cambridge, Mass.: Report for Project on Managing the Atom, Belfer Center for Science and International Affairs, Harvard Kennedy School, December 2003.
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